Khachanov won the pair's previous encounter in Paris - at 2018 Paris Masters, when the Russian claimed a straight-set win in the final to clinch the biggest title of his career until now.
Colombia will face Venezuela in Barranquilla on Friday and Chile in Santiago four days later.
Rodrigo Ely's 74th minute header, following a free kick, gave Alaves its first win of the season at home to Athletic Club Bilbao, who again disappointed just three days after suffering a home defeat to Cadiz and has dropped to second from bottom in the table.
Burel wasted three set points when she took a 5-3 lead in the first set and stormed to 40-0 in the ninth game. But Zhang battled back to save all three, and held the serve before breaking Burel's in the tenth to level the score at 5-5.
The 33-year-old had scored 45 goals in 68 games and won two A-league championships since he joined the Sky Blues in August 2018.
Alvaro Ordiozola will continue at right back after Dani Carvajal suffered a knee injury on Friday that will sideline him for a couple of months, while Ferland Mendy will likely return on the left after being rested in the narrow midweek win at home to Valladolid.
The 12th seed poured out his intense emotions on the court, yelling at himself or his coaches after wasting several chances.
One suspects that Messi, who will be 35 when the next edition of football's showpiece tournament begins, will be a man on a mission during these qualifiers as he seeks to enhance his own legacy and end Argentina's nearly three-decade wait for major silverware.
BUENOS AIRES, Oct. 5 (Xinhua) -- Boca Juniors midfielder Ivan Marcone has joined Spanish side Elche on a season-long loan, the Argentinian club said on Monday.
The NHL and NHLPA previously set Dec. 1 as the tentative start date for next season, with training camp opening Nov. 17. But Bettman stated multiple times that the dates could be pushed back if necessary.
Dominic Calvert-Lewin's 16th minute header put Everton ahead but Brighton equalized through Neal Maupay after a Jordan Pickford error.